XG-Cr3+凝胶改良黏土工程特性及微观作用机制

Engineering properties and microscopic mechanism of clay improved by XG-Cr3+ hydrogel

  • 摘要: 本研究旨在验证Cr3+诱导黄原胶(XG)交联(简称为XG-Cr3+凝胶)对黏土的改良效果,首先研究了XG-Cr3+凝胶的水敏性、粘度等物理特性,随后通过无侧限抗压强度试验与水稳定性试验研究了Cr3+对XG凝胶改良黏土效果的影响,最后借助SEM、FTIR测试揭示了XG-Cr3+凝胶改良黏土的微观机制。结果表明:(1) Cr3+掺入能够大幅缩减XG溶液的成胶时间,且凝胶状态坚挺,并有效改善XG凝胶的水敏性,降低粘度,加速凝胶过程。(2) 随Cr3+掺量和养护时间增加,改良黏土抗压强度明显增强,表现出明显的应变软化特征,试样以贯通裂隙破坏为主,裂隙多呈“Y”型。 (3) Cr3+掺入能够显著提高改良黏土的水稳定性,延长土样崩解时间(XG-Cr3+凝胶改良黏土在测试时间内保持结构完整),显著降低崩解指数(SI)值,且不同时刻的SI值均随Cr3+掺量和养护时间增加逐渐减小。(4) 在XG溶液中掺入适量的Cr3+后,其通过与XG分子链上官能团的金属配位作用促进XG分子间和分子内交联,提高XG凝胶强度,降低水敏性,从而增强湿态下黏土的强度和水稳定性。XG-Cr3+凝胶的这种作用与XG浓度、Cr3+掺量、养护时间密切相关。本研究中,在1%XG中掺入30%Cr3+养护14d时黏土加固效果更为显著。

     

    Abstract: This study aims to verify the improvement effect of Cr3+ -induced xanthan gum (XG) cross-linking (referred to as XG-Cr3+ hydrogel for short) on clay. Firstly, the physical properties such as water sensitivity and viscosity of XG-Cr3+ hydrogel were studied. Subsequently, the influence of Cr3+ on the improvement effect of XG hydrogel on clay was investigated through unconfined compressive strength tests and water stability tests. Finally, the microscopic mechanism of XG-Cr3+ hydrogel in improving clay was revealed by means of SEM and FTIR tests. The results show that: (1) The incorporation of Cr3+ can significantly reduce the gelation time of the XG solution, and the hydrogel state is firm. It can also effectively improve the water sensitivity of the XG hydrogel, reduce the viscosity, and accelerate the gelation process. (2) With the increase of Cr3+ dosage and curing time, the compressive strength of the improved clay is significantly enhanced, showing obvious strain softening characteristics. The specimens are mainly damaged by through fractures, and the fractures are mostly in the shape of "Y". (3) The incorporation of Cr3+ can significantly improve the water stability of the improved clay, prolong the disintegration time of the soil sample (the XG-Cr3+ hydrogel improved clay maintains structural integrity within the test time), significantly reduce the disintegration index (SI) value, and the SI values at different times gradually decrease with the increase of Cr3+ dosage and curing time. (4) After adding an appropriate amount of Cr3+ to the XG solution, it promotes intermolecular and intramolecular cross-linking of XG through metal coordination with the functional groups on the XG molecular chain, enhances the hydrogel strength of XG, reduces water sensitivity, and thereby increases the strength and water stability of the clay in a wet state. This effect of XG-Cr3+ hydrogel is closely related to the concentration of XG, the dosage of Cr3+ and the curing time. In this study, the clay reinforcement effect was more significant when 30%Cr3+ was added to 1%XG and cured for 14 days.

     

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