多功能E-TPU电磁屏蔽泡沫材料的制备及其性能

Preparation and performance research of multifunctional conductive E-TPU foam materials

  • 摘要: 热塑性聚氨酯发泡珠粒(E-TPU)是一种轻质高弹的闭孔泡沫材料,超临界发泡工艺赋予其优异的力学性能,但功能化应用仍面临挑战。本研究通过喷涂/模压复合成型工艺,成功制备了具有多功能的E-TPU@Ag复合泡沫材料,并对其电磁屏蔽、压力传感、焦耳热方面的性能进行系统研究。结果表明,当导电料添加量仅为2wt%时,材料表现出61.2 dB的高电磁屏蔽效能;压力传感测试显示30 ms的快速响应时间和0.18 kPa−1的灵敏度;焦耳热实验中,3 V驱动电压下可实现78.8℃的稳定升温并持续150 s。该项工作为多功能化聚合物泡沫材料的开发提供了可行策略。

     

    Abstract: Thermoplastic polyurethane (TPU) foam beads (E-TPU) are a lightweight, highly elastic, closed-cell foam material. A supercritical foaming process provides this material with excellent mechanical properties. However, its functional applications face challenges. In this study, a multifunctional E-TPU@Ag composite foam material was successfully prepared. A spray/mold pressing composite process was used. The electromagnetic shielding, pressure sensing, and Joule heating performance of the composite were systematically investigated. Results show that the material achieves a high electromagnetic shielding effectiveness of 61.2 dB. This performance requires only 2wt% conductive filler. Pressure sensing tests demonstrate a fast response time of 30 ms and a sensitivity of 0.18 kPa−1. In the Joule heating experiment, the composite reaches a stable temperature increase of 78.8℃. This occurs under a 3 V driving voltage and lasts for 150 s. This work provides a feasible strategy for developing multifunctional polymer foam materials.

     

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