TiO2/Au复合纳米线结构材料的制备与光热性能

Preparation and Photothermal Performance of TiO2/Au Composite Nanowire Structure Material

  • 摘要: 二氧化钛(TiO2)作为钛的氧化物半导体材料,由于化学性质稳定、高折射率及无毒等特点,被广泛应用于光收集。但是,TiO2因固有宽带隙的缘故,只对紫外光波段有较强的响应。本文采用水热合成及磁控溅射工艺在碳布纤维表面构筑了一种二氧化钛纳米线与金纳米颗粒的复合纳米线结构(TiO2/Au NWs),结合二氧化钛纳米线的陷光效应与金纳米颗粒的局域表面等离激元效应,提升TiO2材料在全光谱(200 nm 至 2500 nm)范围的光吸收及光热转换性能。通过结构及组分的调控获得了具有高效宽带光吸收及光热转换性能的TiO2/Au 复合纳米线结构材料,其在全光谱(200 nm至2500 nm)范围光吸收率均高于90%,太阳光吸收率达到约95%,一个太阳光强辐照下表面温度达到约76℃。该TiO2/Au复合纳米线结构设计能够有效拓展TiO2材料的吸收光谱,提升其光热性能及光催化性能,推动TiO2材料在太阳能光热及光催化领域的应用。

     

    Abstract: Titanium dioxide (TiO₂), as an oxide semiconductor material of titanium, has been widely employed in light harvesting due to its stable chemical properties, high refractive index, and non-toxicity. However, TiO₂ only has a strong response to ultraviolet light due to its inherent wide bandgap. Here, a composite structural material (TiO₂/Au NWs) composed of titanium oxide nanowires and gold nanoparticles was fabricated through hydrothermal synthesis and magnetron sputtering processes. This innovative design synergistically integrates the light-trapping effect of TiO₂ nanowires with the localized surface plasmon resonance (LSPR) of Au nanoparticles, thereby significantly enhancing the broadband light absorption capacity and photothermal conversion efficiency of TiO₂ materials in the full spectral range (200 nm to 2500 nm). Through structural and compositional optimization, the developed TiO₂/Au composite nanowire architecture demonstrates exceptional broadband light absorption with consistent absorption rates exceeding 90% across the full spectrum (200 nm to 2500 nm), achieving a solar absorption about 95% and a surface temperature about 76°C under one-sun irradiation. The TiO₂/Au composite nanostructure design effectively extends the absorption spectrum of TiO₂-based materials while enhancing both photothermal and photocatalytic performance, thereby advancing the application of TiO₂ materials in solar thermal conversion and photocatalytic fields.

     

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