深色石墨相氮化碳的调控合成及其光催化性能研究进展

Research progress for the controlled synthesis and photocatalytic performance of deep-coloredgraphitic carbon nitride

  • 摘要: 石墨相氮化碳(g-C3N4)具有稳定性好、禁带宽度适中、可见光响应良好等优点,是一种备受关注的光催化材料,但是g-C3N4自身存在的可见光吸收范围窄,比表面积低,电荷载流子分离和传输效率低等缺点,阻碍了其实际应用。大量研究表明,通过加深光催化材料的颜色可以提高其可见光的吸收范围,从而使更多的光能被吸收和利用,同时加快了电荷载流子的分离和传输。常规制备方法所得的g-C3N4为淡黄色粉末,通过缺陷工程、元素掺杂、形貌调控等方式可制备出深色的g-C3N4粉末,如向g-C3N4中引入氮缺陷、氰基缺陷等缺陷;或是引入溴、氧等元素掺杂;又或者是提高g-C3N4的结晶度和其他特殊形貌的调控。本文首先介绍了深色g-C3N4的优势和近年来的发展状况,然后从深色g-C3N4的调控方法、结构表征、光催化性能和应用等方面进行了全面的综述,最后对深色g-C3N4未来结构调控策略的发展趋势,以及面临的颜色变化机理和光吸收性能贡献率等挑战进行了总结和展望。

     

    Abstract: Graphitic carbon nitride (g-C3N4) is a highly concerned photocatalytic material, renowned for its excellenttability, suitable band gap, and favorable visible-light responsiveness. However, inherent drawbacks such as narrow visible-light absorption range, low specific surface area, and inefficient charge-carrier separation and transport significantly impede its practical use.Extensive research indicates that darkening the color of photocatalytic materials can effectively broaden their visible-light absorption spectrum, which not only enhances the utilization of light energy but also accelerates charge-carrier separation and transport efficiency. Conventionally synthesized g-C3N4 typically appears as a light-yellow powder. In contrast, strategies such as defect engineering, element doping, and morphology controlling can be employed to prepare dark-colored g-C3N4 powders. These strategies involve introducing defects like nitrogen or cyano defects into g-C3N4, doping with elements such as bromine or oxygen, or modifying the crystallinity and morphology of g-C3N4.This paper gives an overview ofthe advantages of dark-colored g-C3N4 and its recent progress. Subsequently, the preparation methods, structural characterization, photocatalytic performance, and applications for dark-colored g-C3N4were introduced.Finally, the development trends of future structural regulation strategies for dark g-C3N4, as well as the challenges it faces, such as the mechanism of color change and the contribution rate of light absorption performance, are summarized and prospected.

     

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