热老化对耐高温环氧模塑料的性能影响研究

Study on the Effect of Thermal Aging on the Properties of High-Temperature-Resistant Epoxy Molding Compounds

  • 摘要: 随着第三代半导体器件工作温度的升高,传统环氧模塑料(EMC)因玻璃化转变温度(Tg)较低,难以满足高温大功率器件的封装需求。为解决这一问题,本研究开发了一种玻璃化转变温度达260℃的氰酸酯基环氧模塑料,并在150℃、175℃和200℃温度下进行热老化试验。结果表明,该EMC在老化初期储能模量显著提升,击穿场强保持在40 kV/mm以上,热分解温度略有下降。老化15天后,在200℃条件下储能模量下降12.8%,击穿场强下降15.2%,但仍高于35 kV/mm,介电常数和介电损耗角正切值也处于较低水平。热导率在老化初期下降幅度较大,但随着老化时间延长,下降速度减缓。这些结果表明,该环氧模塑料在高温老化条件下展现出优异的热稳定性和绝缘性能,具有广阔的应用前景。

     

    Abstract: As the operating temperature of third-generation semiconductor devices increases, traditional epoxy molding compounds (EMC) with low glass transition temperatures (Tg) fail to meet the packaging requirements of high-temperature, high-power devices. To address this issue, this study has developed a cyanate ester-based epoxy molding compound with a glass transition temperature of up to 260℃ and subjected it to thermal aging tests at temperatures of 150℃, 175℃, and 200℃. The results showed that the storage modulus of the EMC significantly increased in the initial stage of aging, while the breakdown field strength remained above 40 kV/mm and the thermal decomposition temperature slightly decreased. After 15 days of aging, the storage modulus decreased by 12.8% and the breakdown field strength decreased by 15.2% under the condition of 200℃, but it was still higher than 35 kV/mm. The dielectric constant and the tangent of the dielectric loss angle were also at low levels. The thermal conductivity decreased sharply in the early stage of aging but the rate of decrease slowed down as the aging time extended. These results indicate that this epoxy molding compound exhibits excellent thermal stability and insulation properties under high-temperature aging conditions and has a broad application prospect.

     

/

返回文章
返回