碳纤维增强煤矸石-矿渣基地聚合物力学性能演变与孔结构分析

Mechanical Properties Evolution and Pore Structure Analysis of Carbon Fiber Reinforced Coal Gangue-GGBS Base Polymer

  • 摘要: 针对煤矸石-矿渣基地聚合物(Coal Gangues-GGBS Geopolymer,CGS)强度低、脆性大等缺陷,本研究引入碳纤维(Carbon Fibre,CF)改善CGS性能以高效利用。以球磨后的煤矸石、矿渣为前驱体,水玻璃为激发剂制备地聚合物。通过设置标准养护与60 ℃养护两种条件,考察不同体积掺量的CF对CGS抗压、抗折强度、断裂韧性、流变行为、孔结构及干燥收缩的影响。研究表明:CF显著改善了CGS的综合性能,掺量为0.6%时,标准养护与60℃养护下的28 d抗压强度分别达17.00 MPa与24.80 MPa,较基准组提升28.30%与44.19%;起裂韧度、失稳韧度分别提升了64.88%/47.91%(标准养护/60℃养护)和66.75%/48.11%。流变分析显示,触变性能、屈服应力、塑性黏度均随CF掺量的提升而提升。微观分析表明,CF与基体紧密结合,适量的引入可以优化孔隙结构,降低孔隙率并提高基体的致密性。

     

    Abstract: In view of the low strength and brittleness of coal gangue slag geopolymer (CGS), carbon fiber (CF) was introduced to improve the performance of CGS for efficient utilization.The geopolymer was prepared using ball-milled coal gangue and GGBS as precursors with sodium silicate as the activator. Two curing conditions: standard curing and 60℃ curing, were applied to explore the effects of different CF volume fractions on the Compressive and flexural strength, fracture toughness, rheological behavior, pore structure and drying shrinkage of CGS. The results showed that CF content significantly improved the overall performance of CGS. At the CF content of 0.6%, the 28-day compressive strength under standard curing and 60℃ curing reached 17.00 MPa and 24.80 MPa, respectively, improving by 28.30% and 44.19% compared to the reference group. The crack initiation toughness and instability toughness increased by 64.88%/47.91% (standard/60℃ curing) and 66.75%/48.11% (standard/60℃ curing), respectively. Rheological analysis revealed that CF reduced flowability, but improved thixotropy, yield stress, and plastic viscosity. CF also reduced drying shrinkage through a three-dimensional network structure; at a 1.0% CF content, the 28-day drying shrinkage rate decreased by 23.98% (standard curing) and 40.56% (60℃ curing) compared to the reference group.The micro analysis shows that CF is closely combined with the matrix, and the appropriate introduction can optimize the pore structure, reduce the porosity and improve the compactness of the matrix.

     

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