埃洛石-氢氧化铝协效阻燃增强乙烯醋酸乙烯共聚物-聚乙烯复合体系

Synergistic flame-retardant and strengthened ethylene vinyl acetate copolymer-polyethylene composite using halloysite nanotube and aluminum hydroxide

  • 摘要: 乙烯醋酸乙烯共聚物(EVA)基复合材料的易燃问题极大限制了其在电线电缆工业中作为终端产品的应用。针对传统的金属氢氧化物阻燃剂阻燃效率不高,且与聚合物基体相容性差导致力学性能损失的问题,将传统的无机阻燃剂氢氧化铝(ATH)与埃洛石纳米管(HNT)相结合,构筑氢氧化铝/埃洛石(ATH-HNT)双填料改性乙烯醋酸乙烯共聚物-聚乙烯(EVA-PE)复合体系。系统研究了ATH-HNT双填料体系对EVA-PE复合材料热稳定性、阻燃性能、流变性能以及力学性能的影响。结果表明:与仅加入60wt% ATH相比,在复合体系中同时加入59wt% ATH和1wt% HNT时,热释放速率峰值、总热释放量和总烟释放量分别降低了42.1%,33.7%和43.6%,有效降低了材料的燃烧强度和有毒烟气的释放。此外,拉伸强度和断裂伸长率分别增加了25.9%和71.8%。阻燃机制分析表明,少量HNT的加入可以改善ATH的分散性,促进填料网络在聚合物基体中的形成,从而有助于燃烧过程中形成致密的炭层。本研究为获得高性能电线电缆复合材料提供了可行的思路和策略。

     

    Abstract: The flammability of ethylene vinyl acetate copolymer (EVA) based composite materials greatly limits their application as terminal products in the wire and cable industry. The traditional metal hydroxide flame retardants show low flame-retardant efficacy and poor compatibility with the polymer matrix, which usually results in the loss of mechanical properties. To address the drawbacks, a dual inorganic filler system was constructed by combining the traditional inorganic flame-retardant aluminum hydroxide (ATH) and the halloysite nanotube (HNT) and introduced to ethylene vinyl acetate copolymer-polyethylene (EVA-PE) composite. The thermal stability, flame retardancy, rheological properties and mechanical properties of the resulting EVA-PE composites were systemically investigated. The results demonstrate that peak heat release rate (PHRR), total heat release (THR) and total smoke production (TSP) of EVA-PE composite containing 59wt% ATH and 1wt% HNT decrease by 42.1%, 33.7% and 43.6%, respectively, when compared to EVA-PE composite with only 60wt% ATH. The combustion intensity and the release of toxic smoke are decreased significantly. Besides, the tensile strength and elongation at break of ATH59-HNT1/EVA-PE increase by 25.9% and 71.8%, respectively. The flame retardant mechanism analysis shows that the incorporated HNT can improve the ATH dispersion and promote the filler network formation in the polymer matrix, which is beneficial to the formation of consistent char layer during combustion. This work proposes a feasible strategy for obtaining high performance composites for wire and cable industry.

     

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