热处理钻井岩屑/壳聚糖复合气凝胶的制备及表征

Synthesis and characterization of the heat-treated drill cuttings/chitosan composite aerogel

  • 摘要: 为了提高壳聚糖气凝胶(CA)的力学性能和稳定性,使其具有更好的应用前景。基于溶胶-凝胶法制备了一种热处理钻井岩屑(TTDC)/壳聚糖复合气凝胶(TTDC/CA),并对材料的结构、组成、稳定性和力学性能等进行了表征和测试。结果表明,所制备的复合气凝胶为多孔结构且表现出各向异性的特点,TTDC添加量会显著影响材料的孔结构特征。TTDC提高了复合气凝胶的比表面积,添加3wt%的TTDC时,复合气凝胶的比表面积可达12.883 m 2/g,接近CA的两倍。适量添加TTDC还可以提高复合气凝胶的机械压缩性及其在酸性环境中的耐受能力,pH = 2时,添加3wt%的TTDC就可以使CA的质量损失减少46%。该复合气凝胶制备过程简单、快速,为钻井岩屑的高附加值利用提供了新的思路,在环境修复等领域具有良好的应用潜力。

     

    Abstract: In order to improve the mechanical properties and stability of chitosan aerogel (CA) and make it have better application prospects. In this study, a thermal treated drilling cuttings (TTDC)/chitosan composite aerogel (TTDC/CA) was prepared based on the sol gel method, and the structure, composition, stability and mechanical properties of the material were characterized and tested. The results show that the composite aerogel is porous and exhibits anisotropic, and the TTDC affects the pore structure of the material. TTDC increased the specific surface area of the composite aerogel. With 3wt% TTDC added, the specific surface area of composite aerogel reached 12.883 m 2/g, nearly twice that of CA. TTDC can also improve the mechanical compressibility and acid resistance of composite aerogels. At pH = 2, the addition of 3wt% TTDC reduced the mass loss of CA by 46%. The preparation of this composite aerogel is simple and rapid, which has good potential for application in areas such as environmental remediation.

     

/

返回文章
返回