3D打印纳米碳填料/连续玄武岩纤维增强超混杂复合材料层间性能研究

Study on interlaminar properties of 3D printed carbon nanofiller/continuous basalt fiber reinforced super-hybrid composites

  • 摘要: 连续纤维增强聚合物复合材料(CFRPC)具有优异的力学性能、耐腐蚀性和轻质特性,广泛应用于众多领域。然而,3D打印逐层堆积产生的层间力学性能不足导致由该工艺方式制备的CFRPC易分层失效,结构性能变得不稳定,增加了设计难度和使用风险,限制了其在高技术领域的应用。为此,对熔丝制造超混杂氧化石墨烯(GO)和碳纳米管(CNTs)增强的连续玄武岩纤维/聚酰胺基复合材料进行了研究。0.8wt%的GO引入使CFRPC横向拉伸强度提升111.2%、横向拉伸模量提高184.3%、层间剪切强度提高24.2%、Ⅱ型断裂韧性提高174.2%;1.5wt%的CNTs的引入使CFRPC横向拉伸强度提升34.2%、横向拉伸模量提高135.8%、层间剪切强度提高18.1%、Ⅱ型断裂韧性提高165.1%。结合SEM分析,片层GO通过增强界面化学键合、利用褶皱结构、形成三维连续网络来提升层间性能,管状CNTs阻碍分子链缠绕,并通过桥联改善CFRPC层间性能。通过多尺度协同增强设计,阐明了纳米填料调控基体强化、界面改善及裂纹扩展的机制,为开发高性能3D打印复合材料提供了理论依据,在航空航天、汽车制造等领域具有重要应用潜力。

     

    Abstract: Continuous fiber reinforced polymer composites (CFRPC) possess outstanding mechanical properties, corrosion resistance and lightweight characteristics, and thus have been widely applied in various fields. However, due to interlaminar defects inherent to the layer-by-layer deposition process are attributed to the insufficient interlaminar mechanical properties of 3D printed CFRPC, CFRPC is prone to delamination failure. That makes the structural properties become unstable, increases the risk of design and use, and limits its applications in high-tech fields. In this study, continuous basalt fiber/polyamide composites modified with graphene oxide (GO) and carbon nanotubes (CNTs) were fabricated by fused filament fabrication technology and studied. The addition of 0.8wt% GO increased the transverse tensile strength of CFRPC by 111.2%, the transverse tensile modulus by 184.3%, the interlaminar shear strength by 24.2%, and the mode II interlaminar fracture toughness by 174.2%. The addition of 1.5wt% CNTs increased the transverse tensile strength of CFRPC by 34.2%, the transverse tensile modulus by 135.8%, the interlaminar shear strength by 18.1%, and the mode II interlaminar fracture toughness by 165.1%. Combined with SEM image analysis, lamellar GO improved the inter-layer properties by enhancing the interfacial chemical bonding, having the aid of wrinkle structure, and forming three-dimensional continuous networks; on the other hand, tubular CNTs improved the inter-layer properties of CFRPC by preventing the entanglement of molecular chains and bridging. Through multi-scale collaborative reinforcement design, matrix strength and interface strength enhancements and crack propagation path regulated by nanofillers were clarified as the strengthening mechanisms. This study provides a theoretical basis for the development of high-performance 3D printed composite materials which have important application potential in aerospace, automotive manufacturing and other fields.

     

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